Dimer formation in the trityl cationic polymerization of styrene oxide
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منابع مشابه
Nitroxide-Mediated Radical Polymerization of Styrene Initiated from the Surface of Titanium Oxide Nanoparticles
Titanium dioxide (TiO2) nanoparticles, with an average size of about 45 nm, were encapsulated by polystyrene using in situ nitroxide mediated radical polymerization in the presence of 3-aminopropyl triethoxy silane (APTES) as a coupling agent and 2, 2, 6, 6-tetramethylpiperidinyl-1-oxy as a initiator. First, the initiator for NMRP was covalently bonded onto the surface of Titanium dioxide na...
متن کاملReactivity of heteropolymolybdates and heteropolytungstates in the cationic polymerization of styrene.
The two heteropolyacids H(3)PW(12)O(40) and H(3)PMo(12)O(40), and their homologous salts (NH(4))(3)PW(12)O(40), and (NH(4))(3)PMo(12)O(40) were prepared and tested in the cationic polymerization of styrene. The results showed that the heteropolytungstates were more reactive than the heteropolymolybdates. It has been found that the yield and the viscosity average molecular weight (M(v)) of polys...
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Styrene can be polymerized at room temperature in the presence of equimolar mixtures of the gold(III) complexes (NHC)AuBr3 (NHC = N-heterocyclic carbene ligand) and NaBAr'4, in the first example of a gold-induced olefin polymerization reaction.
متن کاملnitroxide-mediated radical polymerization of styrene initiated from the surface of titanium oxide nanoparticles
titanium dioxide (tio2) nanoparticles, with an average size of about 45 nm, were encapsulated by polystyrene using in situ nitroxide mediated radical polymerization in the presence of 3-aminopropyl triethoxy silane (aptes) as a coupling agent and 2, 2, 6, 6-tetramethylpiperidinyl-1-oxy as a initiator. first, the initiator for nmrp was covalently bonded onto the surface of titanium dioxide na...
متن کاملPhotoinitiated Polymerization of Styrene in Microemulsions
Photoinitiated polymerization of styrene in oil/water microemulsions has been successfully performed by using dibenzyl ketone (DBK) as initiator. The system remains transparent during the whole polymerization process. The molecular weights of polymers produced are in the order of IO5, and the polydispersity indexes (PDI) are in the range 1.6-2.2. The particle sizes of the latexes produced are i...
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ژورنال
عنوان ژورنال: Journal of Polymer Science Part A: General Papers
سال: 1965
ISSN: 0449-2951,1542-6246
DOI: 10.1002/pol.1965.100031225